Santiago Barroso Ivars

s a n t i a g o . b a r r o s o (a) g m a i l . c o m

I am Graduated in Chemistry and Doctor in Organic Chemistry for the Universitat de València (Spain). Currently I am a postdoctoral researcher in the Bio-Chemistry Department of the Rijksuniversiteit Groningen (The Netherlands), under the direction of Prof. Dr. Adriaan Minnaard.   I invite you to visit my Photographic Gallery with some of my best photographic works.   Santiago Barroso Ivars

 

Research Topics:

 Oxidative catalysis, diastereoselective reactions, enantioselective catalysis and asymmetric synthesis of natural products.

Publications in scientific journals:

Organic Letters 2011, 13 (3), 402–405

Highly Enantioselective Nitrone Cycloadditions with 2-Alkenoyl Pyridine N-Oxides Catalyzed by Cu(II)-BOX Complexes Santiago Barroso, Gonzalo Blay*, M. Carmen Muñoz, José R. Pedro*

Advanced Synthesis & Catalysis 2009, 351, 107-11

Highly enantio- and diastereoselective inverse-electron demand hetero-Diels-Alder reaction using 2-alkenoyl pyridine N-oxides as oxo-heterodienes Santiago Barroso, Gonzalo Blay*, M. Carmen Muñoz, José R. Pedro*

Journal of Organic Chemistry 2008, 73 (16), 6389–6392

Copper(II)−Bis(oxazoline) Catalyzed Asymmetric Diels−Alder Reaction with α′-Arylsulfonyl Enones as Dienophiles Santiago Barroso, Gonzalo Blay*, Lina Al-Midfa, M. Carmen Muñoz, José R. Pedro*

Synlett 2007, 2659-2662

New Chiral Hydroxyoxazolines Based on Ketopinic Acid and Their Use in the Asymmetric Diels-Alder Reaction Santiago Barroso, Gonzalo Blay, Luz Cardona, José R. Pedro*

Organic Letters 2007, 9, 1983-1986

2-Alkenoyl Pyridine N-Oxides, Highly Efficient Dienophiles for the Enantioselective Cu(II)-Bis(oxazoline)Catalyzed Diels-Alder Reaction Santiago Barroso, Gonzalo Blay, José R. Pedro*

Journal of Molecular Catalysis A: Chemical 2005, 243, 214–220

Chemistry and reactivity of mononuclear manganese oxamate complexes: Oxidative carbon–carbon bond cleavage of vic-diols by dioxygen and aldehydes catalyzed by a trans-dipyridine manganese(III) complex with a tetradentate o-phenylenedioxamate ligand Santiago Barroso, Gonzalo Blay, Isabel Fernández, José R. Pedro,* Rafael Ruiz-García, Emilio Pardo, Francesc Lloret, M. Carmen Muñoz

Tetrahedron Letters 2004, 45, 8583–8586

Novel 2-pyrone synthesis via Michael addition of mandelic acid enolate to trans-1,2-diaroylethenes Santiago Barroso, Gonzalo Blay, Isabel Fernández and José R. Pedro*

Journal of Organic Chemistry 2004, 69, 6821-6829

Highly Diastereoselective Arylation of (S)-Mandelic Acid Enolate: Enantioselective Synthesis of Substituted (R)-3-Hydroxy-3-phenyloxindoles and (R)-Benzylic Acids and Synthesis of Nitrobenzophenones Santiago Barroso, Gonzalo Blay, Luz Cardona, Isabel Fernández, Begoña García, and José R. Pedro*

My thesis was on chiral Cu(II) enantioselective catalized cycloaddion reactions. This work was done under the supervision of Prof. Dr. José Ramón Pedro and the Prof. Dr. Gonzalo Blay, from the University of València.

My current work is focused in the synthesis of phenolic glycolipids presents in mycobacterium tuberculosis.

Santiago Barroso Ivars © 2000-2010